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Keyed in multiple places:

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Key to Crassulaceae

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1 Leaves connate at the base, opposite; flowers solitary in the axils of leaves; flowers 3-4-merous; [subfamily Crassuloideae]
1 Leaves distinct, whorled or alternate; flowers in terminal cymose inflorescences; flowers 4-5 (-8)-merous.
  2 Petals connate as a tube; leaves serrate, bearing plantlets in the serrations; [subfamily Kalanchoideae]
  2 Petals distinct or at most basally connate; leaves entire, crenate, or serrate, but not bearing plantlets along the margin; [subfamily Sempervivoideae].
    3 Plants with spheroidal basal rosettes consisting of dozens or more spirally arranged leaves; flowers 8-16-merous
    3 Plants with or without basal rosettes (if rosettes present, these not as above); flowers 4-6-merous
      4 Flowers (5-) 7 (-9)-merous
      4 Flowers 4-5-merous.
        5 Perennials without rosettes, the stems 0.5-10 dm tall (dying back in winter to the rootstock); leaves large, relatively thin in texture, usually 5-25 times as wide as thick, often crenate; flowers pink, purple, white, or greenish.
          6 Flowers 5-merous, bisexual; flowering stems 2-10 dm tall, from an underground, tuberous base; average leaves 3-11 cm long, 1-5 cm wide; ovaries attenuate at the base; [tribe Telephieae]
          6 Flowers 4 -(5)-merous, usually unisexual and then the plants dioecious; flowering stems 0.5-4 dm tall, from axils of brown scale-leaves clothing a stout rootstock at least in part exposed aboveground; average leaves 1-5 cm long, 0.4-1.5 cm wide; ovaries not attenuate at the base; [tribe Umbiliceae]
        5 Perennials or annuals with or without rosettes, the stems < 2 dm tall (the perennials with stems persistent through the winter); leaves smaller, flat or terete, relatively thicker, entire; flowers white or yellow; [tribe Sedeae].
             7 Leaves flat; leaf margins toothed or crenate.
               8 Leaves alternate; petals yellow
               8 Leaves opposite; petals white to pink
             7 Leaves flat, subterete, or terete; leaf margins entire.
                 9 Carpels united basally (to about 1/3 their length); petals cucullate, initially partly enclosing 4 of the 8 stamens; follicles dehiscing by a tear-shaped valve on the lower surface; stem and leaves normally red; [of granitic flatrocks of the Piedmont of GA, NC, SC, and VA, and sandstone glades in TN, nw. GA, and AL]
                 9 Carpels free; petals flat, never enclosing any of the 8 anthers; follicle dehiscing by a longitudinal slit along the adaxial (upper) suture; stem and leaves normally green, sometimes somewhat pink or reddish; [collectively of various habitats, including similar habitats as Diamorpha]

Key Q: herbaceous dicots with whorled leaves on the stem {add [Platycodon] CAMPANULACEAE}

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  2 Cauline leaves essentially sessile, and also palmately cleft to the base, and further lacerately divided into linear or oblanceolate segments
  2 Cauline leaves petiolate, with 3-5, sessile or petiolulate, ovate, elliptic, or obovate leaflets (these serrate and sometimes with additional lobes).
    3 Inflorescence a spherical umbel of many flowers; fruit a drupe with 2-3 seeds; stem leaves 3-5
      4 Leaflets 3 (-5), sessile or subsessile, the petiolules 0-3 mm long; larger leaflets 4-8 cm long, 0.5-2.5 cm wide, averaging about 2.5× as long as wide, the apex obtuse to acute; fruit yellow-green when ripe, longitudinally winged and ribbed in ×-section; petals white (rarely tinged with pink); inflorescence nodding in bud; underground storage organ a spherical tuber
      4 Leaflets (3-) 5, petiolulate, the petiolules (7-) 10-25 mm long; larger leaflets 6-15 cm long, 3.5-7 cm wide, averaging about 1.8× as long as wide, the apex acuminate; fruit bright red when ripe, smoothly elliptical in ×-section; petals light green; inflorescence erect in bud; underground storage organ an +/- elongate root, this vertical or horizontal, and sometimes branched
    3 Inflorescence of single terminal flowers on the 1-several branches; fruit an aggregate of achenes; stem leaves 3
1 Cauline leaves simple.
        5 Inflorescence an involucrate head subtended by phyllaries, heads solitary or many, variously arrayed in secondary inflorescences; fruit a cypsela
        5 Inflorescence various, but not as above; fruit various, not as above (sometimes the flowers tightly grouped, but then with other features differing, such as stamens 4, or green calyx present, or fruit a schizocarp of mericarps, etc.).
          6 Fruit a 3-lobed, 3-locular capsule; inflorescence a cyathium, consisting of a single pistillate flower (reduced to a single 3-carpellate pistil) and 2 or more staminate flowers (each reduced to 1 stamen), borne in a cup-like involucre, the involucre bearing pointed or rounded glands, these sometimes brightly colored and petaloid, mimicking an individual flower (the cyathia then secondarily arranged in terminal cymes, or solitary and axillary, etc.); fresh plants with milky juice
          6 Fruit various, not as above; inflorescence not a cyathium (and staminate or bisexual flowers almost always with > 1 stamen); fresh plants lacking milky juice.
             7 Leaves succulent, the terminal whorls closely juxtaposed; pistils 4-5; fruit an aggregate of follicles
             7 Leaves herbaceous, thin in texture, whorls separated; pistil 1, of 2-5 fused carpels; fruit a capsule, achene, or drupe.
               8 Larger whorled leaves on a plant < 10 mm wide [some taxa keyed here and under the second lead].
                   10 Leaves markedly variable in shape or size in each whorl; fruit a capsule; petals 5
                   10 Leaves similar in size and shape in each whorl; fruit dry or fleshy, indehiscent; petals (3-) 4
                     11 Corolla bilaterally symmetrical, the petals connate; carpels 2; stamens 4, 6, or 8.
                     11 Corolla radially symmetrical, the petals separate; carpels 2, 3, or 5; stamens 5, 10, or many.
                          13 Inflorescence an axillary umbel; leaves narrowly linear and more than 10× as long as wide, > 20 mm long and < 2 mm wide; whorls of 3-6 leaves
                          13 Inflorescence a terminal cyme, raceme, panicle, or umbel; leaves as above, or broader in shape, narrower, or shorter; whorls of 3-16 leaves.
               8 Larger whorled leaves on a plant > 10 mm wide.
                                    18 Inflorescence of terminal involucrate clusters; perianth of 6 tepals; fruit an achene; stamens 9; [plants of very dry habitats]
                                    18 Inflorescence various, but not as above; perianth of 2 whorls (the calyx often obsolete in Galium in RUBIACEAE), 3-, 4-, 5-, 6-, or 7-merous; stamens 2-7; [plants of dry-mesic to very wet habitats].
                                           21 Corolla pink-purple, 6-merous, the petals separate and borne on the edge of a hypanthium; stamens 8, 10, or 12; [plants of wetlands]
                                           21 Corolla white, yellow, or greenish, 4-, 5-, or 7-merous, the petals fused at least basally into a tube (falling as a unit), not on a hypanthium; stamens 2, 4, 5, or 7; [plants of mesic habitats].
                                               23 Petals yellowish-white, with prominent green streaks; biennial or monocarpic plant, 10-30 dm tall when fertile; leaves 15-35 cm long
                                               23 Petals white or yellow; perennial plants, 1-15 dm tall; leaves 1-15 cm long.